Some materials are known as brittle because a crack moves easily through components made of such materials. If we investigate a fractured surface of a brittle failure to determine the depth up to which the material is affected by the crack growth, we find that material was influenced to a very shallow depth. Rest of the material remains unaffected. On the contrary, a ductile fracture causes a large amount of plastic deformation to a significant depth.
Brittle fracture in crystalline metals can be classified into two broad groups-intergranular and transgranular. A crack tip of intergranular failure grows along the grain boundaries. Transgranular fracture, on the other hand, occurs through the crack tip propagating within grains. However, cleavage failure within a grain occurs along a weak crystallographic plane. In fact, cleavage fracture is the most brittle form of a fracture and it hardly damages the fractured surfaces. Once the cleavage crack reaches the grain boundary, it finds another favorable orientation in the next grain.
Generally, at lower temperature grain boundaries have more strength than the grains i.e. grains are weaker,so fracture occurs through grains(Transgranular fracture). At high-temperature grain boundaries are weaker regions so fracture occurs through these(Intergranular fracture). There is a particular temperature at which transgranular fracture changes to intergranular fracture, this temperature is known as equicohesive temperature.
Ductile fracture growth occurs due to substantial plastic deformation and creation of microvoids in the vicinity of the crack tip. The material deforms plastically due to micromechanisms, such as nucleation and motion of dislocations, the formation of twins, etc. Engineering materials generally contain second phase particles. Tiny voids are formed at the sides of these particles under the influence of the tensile field of the crack tip. Dislocation motion helps in the formation of these voids. The ductile crack growth occurs by the coalescence of these voids. Fractured surface of a ductile failure shows tiny dimples and gives the surface a rather rough look. In fact, around one such dimple, a second phase particle can be identified. The plastic deformation and coalescence of voids absorb a large amount of energy and, therefore, a crack does not grow easily in ductile materials.
Often it has been found that materials normally ductile at room temperature in ordinary conditions behave as brittle materials under certain special conditions. Steel, which is quite ductile at room temperature, becomes brittle at low temperatures. This explains why welded structures of Liberty ships in World War II failed in the cold waters of the North Atlantic Ocean. Also, the toughness of certain materials is affected considerably by the rate of loading (strain rate).
A thick plate of a regular ductile material may also allow the growth of a crack in a brittle manner. The portion that is deep inside the thick plate (away from free surfaces) is constrained from all sides and large plastic deformations are not possible in the vicinity of the crack-tip. In comparison to thick plates, thin plates are more resistant to to crack growth.